As you have seen, Intel's RAID 1 is limited to two disk drives. You may be able to achieve what you want to do with a RAID 5 or RAID 10 volume, which is supported on your board. Using Intel's guide below will help you decide which one to choose:
http://download.intel.com/support/ch...user_guide.pdf
When using Windows 8, you must use IRST versions 11.6 or 11.7. IRST 11.6 is available on your boards download page.
You should be able to boot from your SSD as a single OS drive when in RAID mode, I've done that many times. If you have the boot order set up correctly in the UEFI/BIOS, with the SSD first, then I'm guessing that you installed Windows to the SSD with your RAID 1 volume on the PC. When more disks are connected to the PC than just the OS drive when installing Windows, it will put the MBR on another drive for some reason. That can confuse the boot order. Only have the SSD connected to your PC when you install Windows.
But, I also think there is also a chance that you did not have the SSD on the Intel SATA ports, but on the ASMedia SATA ports. The two ASMedia ports are at the "top" of the stack of SATA ports, the six Intel ports below them. Check your boards manual if you are not sure. The ASMedia SATA interface will not be active when you install an OS unless you install its driver when that option is available during the installation.



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